Equation of State¶D. Buecker and W. Wagner. Reference Equations of State for the Thermodynamic Properties of Fluid Phase n-Butane and Isobutane. J. Phys. Chem. Ref. Data, 35(2):929–1019, 2006. doi:10.1063/1.1901687.
Thermal Conductivity¶R.A. Perkins. Measurement and Correlation of the Thermal Conductivity of Isobutane from 114 K to 600 K at Pressures to 70 MPa. J. Chem. Eng. Data, 47(5):1272–1279, 2002. doi:10.1021/je010121u.
Viscosity¶E. Vogel, C. Kuechenmeister, and E. Bich. Viscosity Correlation for Isobutane over Wide Ranges of the Fluid Region. Int. J. Thermophys, 21(2):343–356, 2000. doi:10.1023/A:1006623310780.
Melting Line¶D. Buecker and W. Wagner. Reference Equations of State for the Thermodynamic Properties of Fluid Phase n-Butane and Isobutane. J. Phys. Chem. Ref. Data, 35(2):929–1019, 2006. doi:10.1063/1.1901687.
|Molar mass [kg/mol]||0.0581222|
|Maximum temperature [K]||575.0|
|Maximum pressure [Pa]||35000000.0|
|Triple point temperature [K]||113.73|
|Triple point pressure [Pa]||0.0228908390119|
|Critical point temperature [K]||407.817|
|Critical point density [kg/m3]||225.5|
|Critical point density [mol/m3]||3879.75678828|
|Critical point pressure [Pa]||3629000.0|
|Reducing point temperature [K]||407.81|
|Reducing point density [mol/m3]||3879.75678828|
REFPROP Validation Data¶
This figure compares the results generated from CoolProp and those generated from REFPROP. They are all results obtained in the form \(Y(T,\rho)\), where \(Y\) is the parameter of interest and which for all EOS is a direct evaluation of the EOS
You can download the script that generated the following figure here:
(link to script), right-click the link and then save as... or the equivalent in your browser. You can also download this figure
as a PDF.
The following figure shows all the flash routines that are available for this fluid. A red + is a failure of the flash routine, a black dot is a success. Hopefully you will only see black dots. The red curve is the maximum temperature curve, and the blue curve is the melting line if one is available for the fluid.
In this figure, we start off with a state point given by T,P and then we calculate each of the other possible output pairs in turn, and then try to re-calculate T,P from the new input pair. If we don’t arrive back at the original T,P values, there is a problem in the flash routine in CoolProp. For more information on how these figures were generated, see