R40

References

Equation of State

Monika Thol, Lorenzo Piazza, and Roland Span. A New Functional Form for Equations of State for Some Weakly Associating Fluids. Int. J. Thermophys., 35(5):783–811, 2014. URL: http://dx.doi.org/10.1007/s10765-014-1633-1, doi:10.1007/s10765-014-1633-1.

Surface Tension

A. Mulero and I. Cachadiña. Recommended Correlations for the Surface Tension of Several Fluids Included in the REFPROP Program. J. Phys. Chem. Ref. Data, 43:023104–1:8, 2014. doi:10.1063/1.4878755.

Aliases

MethylChloride

Fluid Information

Parameter, Value  
General  
Molar mass [kg/mol] 0.05048752
CAS number 74-87-3
ASHRAE class UNKNOWN
Formula \(CClH_{3}\)
Acentric factor 0.150068496396
InChI InChI=1/CH3Cl/c1-2/h1H3
InChIKey NEHMKBQYUWJMIP-UHFFFAOYAW
SMILES CCl
ChemSpider ID 6087
2D image http://www.chemspider.com/ImagesHandler.ashx?id=6087
Limits  
Maximum temperature [K] 730.0
Maximum pressure [Pa] 100000000.0
Triple point  
Triple point temperature [K] 230.0
Triple point pressure [Pa] 40560.9612761
Critical point  
Critical point temperature [K] 416.3
Critical point density [kg/m3] 363.218982472
Critical point density [mol/m3] 7194.233
Critical point pressure [Pa] 6671686.97714
   

REFPROP Validation Data

Note

This figure compares the results generated from CoolProp and those generated from REFPROP. They are all results obtained in the form \(Y(T,\rho)\), where \(Y\) is the parameter of interest and which for all EOS is a direct evaluation of the EOS

You can download the script that generated the following figure here: (link to script), right-click the link and then save as... or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/R40.png

Consistency Plots

The following figure shows all the flash routines that are available for this fluid. A red + is a failure of the flash routine, a black dot is a success. Hopefully you will only see black dots. The red curve is the maximum temperature curve, and the blue curve is the melting line if one is available for the fluid.

In this figure, we start off with a state point given by T,P and then we calculate each of the other possible output pairs in turn, and then try to re-calculate T,P from the new input pair. If we don’t arrive back at the original T,P values, there is a problem in the flash routine in CoolProp. For more information on how these figures were generated, see CoolProp.Plots.ConsistencyPlots

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as... or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/R401.png