R227EA

References

Equation of State

Eric W. Lemmon and Roland Span. Thermodynamic Properties of R-227ea, R-365mfc, R-115, and R13I1. J. Chem. Eng. Data, 2016, submitted. doi:10.1021/acs.jced.5b00684.

Thermal Conductivity

Marcia L. Huber, Arno Laesecke, and Richard A. Perkins. Model for the Viscosity and Thermal Conductivity of Refrigerants, Including a New Correlation for the Viscosity of R134a. Ind. Eng. Chem. Res., 42:3163–3178, 2003. doi:10.1021/ie0300880.

Viscosity

Marcia L. Huber, Arno Laesecke, and Richard A. Perkins. Model for the Viscosity and Thermal Conductivity of Refrigerants, Including a New Correlation for the Viscosity of R134a. Ind. Eng. Chem. Res., 42:3163–3178, 2003. doi:10.1021/ie0300880.

Surface Tension

A. Mulero, I. Cachadiña, and M. I. Parra. Recommended Correlations for the Surface Tension of Common Fluids. J. Phys. Chem. Ref. Data, 41(4):043105–1:13, 2012. doi:10.1063/1.4768782.

Aliases

R227ea

Fluid Information

Parameter, Value

General

Molar mass [kg/mol]

0.17002886

CAS number

431-89-0

ASHRAE class

A1

Formula

C3F7H

Acentric factor

0.3576412419532815

InChI

InChI=1S/C3HF7/c4-1(2(5,6)7)3(8,9)10/h1H

InChIKey

YFMFNYKEUDLDTL-UHFFFAOYSA-N

SMILES

C(C(F)(F)F)(C(F)(F)F)F

ChemSpider ID

61257

Limits

Maximum temperature [K]

475.0

Maximum pressure [Pa]

60000000.0

Triple point

Triple point temperature [K]

146.35

Triple point pressure [Pa]

7.331559169108263

Critical point

Critical point temperature [K]

374.9001034452502

Critical point density [kg/m3]

594.2469253739447

Critical point density [mol/m3]

3494.976825545644

Critical point pressure [Pa]

2925248.665680179

REFPROP Validation Data

Note

This figure compares the results generated from CoolProp and those generated from REFPROP. They are all results obtained in the form \(Y(T,\rho)\), where \(Y\) is the parameter of interest and which for all EOS is a direct evaluation of the EOS

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/R227EA.png

Consistency Plots

The following figure shows all the flash routines that are available for this fluid. A red + is a failure of the flash routine, a black dot is a success. Hopefully you will only see black dots. The red curve is the maximum temperature curve, and the blue curve is the melting line if one is available for the fluid.

In this figure, we start off with a state point given by T,P and then we calculate each of the other possible output pairs in turn, and then try to re-calculate T,P from the new input pair. If we don’t arrive back at the original T,P values, there is a problem in the flash routine in CoolProp. For more information on how these figures were generated, see CoolProp.Plots.ConsistencyPlots

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/R227EA1.png

Superancillary Plots

The following figure shows the accuracy of the superancillary functions relative to extended precision calculations carried out in C++ with the teqp library. The results of the iterative calculations with REFPROP and CoolProp are also shown.

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/R227EA2.png