MethylLinolenate#

References#

Equation of State#

Marcia L. Huber, Eric W. Lemmon, Andrei Kazakov, Lisa S. Ott, and Thomas J. Bruno. Model for the Thermodynamic Properties of a Biodiesel Fuel. Energy & Fuels, 23:3790–3797, 2009. doi:10.1021/ef900159g.

Aliases#

METHYLLINOLENATE, MLINOLEN

Molecular Structure#

MethylLinolenate — 3D conformer (interactive: click and drag to rotate)

Fluid Information#

Parameter, Value

General

Molar mass [kg/mol]

0.29245618

CAS number

301-00-8

ASHRAE class

UNKNOWN

Formula

C19H32O2

Acentric factor

1.142605258673496

InChI

InChI=1S/C19H32O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h4-5,7-8,10-11H,3,6,9,12-18H2,1-2H3/b5-4-,8-7-,11-10-

InChIKey

DVWSXZIHSUZZKJ-YSTUJMKBSA-N

SMILES

CC/C=CC/C=CC/C=CCCCCCCCC(=O)OC

ChemSpider ID

4477947

Limits

Maximum temperature [K]

1000.0

Maximum pressure [Pa]

50000000.0

Triple point

Triple point temperature [K]

260.0

Triple point pressure [Pa]

\(7.39936963447781\times 10^{-07}\)

Critical point

Critical point temperature [K]

772.0000022320153

Critical point density [kg/m3]

247.7981283034243

Critical point density [mol/m3]

847.300023899048

Critical point pressure [Pa]

1368997.256542253

REFPROP Validation Data#

Note

This figure compares the results generated from CoolProp and those generated from REFPROP. They are all results obtained in the form \(Y(T,\rho)\), where \(Y\) is the parameter of interest and which for all EOS is a direct evaluation of the EOS

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate.png

Consistency Plots#

The following figure shows all the flash routines that are available for this fluid. A red + is a failure of the flash routine, a black dot is a success. Hopefully you will only see black dots. The red curve is the maximum temperature curve, and the blue curve is the melting line if one is available for the fluid.

In this figure, we start off with a state point given by T,P and then we calculate each of the other possible output pairs in turn, and then try to re-calculate T,P from the new input pair. If we don’t arrive back at the original T,P values, there is a problem in the flash routine in CoolProp. For more information on how these figures were generated, see CoolProp.Plots.ConsistencyPlots

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate1.png

Flash consistency (HEOS): 167 inconsistent, 64 exceptions, 0 bad-phase across 10 input pair(s).

Download full failure list (CSV)

Failing state points (sample, up to 20 per pair/class)

Pair

Class

Region

P [Pa]

T [K]

In1

Val1

In2

Val2

Error

DmolarHmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Hmolar

-233371

DmolarHmolar

INCONSISTENT

1phase

0.00115879

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarP

EXCEPTION

2phase

5.30629e-07

261

Dmolar

3159.34

P

5.30629e-07

Starting value of T0 is not valid in DP_flash

DmolarP

INCONSISTENT

1phase

0.155238

261.1

Dmolar

3159.07

P

0.155238

DmolarP

INCONSISTENT

1phase

0.351154

298.992

Dmolar

3059.71

P

0.351154

DmolarP

INCONSISTENT

1phase

0.794321

298.992

Dmolar

3059.71

P

0.794321

DmolarP

INCONSISTENT

1phase

0.794321

261.1

Dmolar

3159.07

P

0.794321

DmolarP

INCONSISTENT

1phase

0.000512279

261.1

Dmolar

3159.07

P

0.000512279

DmolarP

INCONSISTENT

1phase

0.030339

298.992

Dmolar

3059.71

P

0.030339

DmolarP

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

1.14688e-09

P

5.30629e-07

DmolarP

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

2.41449e-10

P

5.30629e-07

DmolarP

INCONSISTENT

1phase

0.0134123

317.938

Dmolar

3012.49

P

0.0134123

DmolarP

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

P

1.95664e-05

DmolarP

INCONSISTENT

1phase

0.00115879

298.992

Dmolar

3059.71

P

0.00115879

DmolarP

INCONSISTENT

1phase

0.000226469

261.1

Dmolar

3159.07

P

0.000226469

DmolarP

INCONSISTENT

1phase

0.00262122

261.1

Dmolar

3159.07

P

0.00262122

DmolarP

INCONSISTENT

1phase

0.0134123

298.992

Dmolar

3059.71

P

0.0134123

DmolarP

INCONSISTENT

1phase

0.0134123

261.1

Dmolar

3159.07

P

0.0134123

DmolarP

INCONSISTENT

1phase

0.00262122

298.992

Dmolar

3059.71

P

0.00262122

DmolarP

INCONSISTENT

1phase

0.351154

336.885

Dmolar

2966.42

P

0.351154

DmolarP

INCONSISTENT

1phase

0.155238

336.885

Dmolar

2966.42

P

0.155238

DmolarP

INCONSISTENT

1phase

0.0686277

280.046

Dmolar

3108.44

P

0.0686277

DmolarP

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

P

1.6905e-06

DmolarSmolar

INCONSISTENT

1phase

0.000226469

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Smolar

-515.922

DmolarT

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

3159.34

T

261

DmolarT

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

2.41449e-10

T

261

DmolarT

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

2phase

7.32374e-05

287.842

Dmolar

3088.18

T

287.842

DmolarT

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

T

280.046

DmolarT

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

T

261.1

DmolarUmolar

INCONSISTENT

1phase

0.000226469

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Umolar

-233371

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-256900

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-256900 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-250692

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-250692 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-244484

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-244484 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-238276

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-238276 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-232068

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-232068 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-225860

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-225860 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-219652

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-219652 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-213444

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-213444 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-207236

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-207236 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-201028

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-201028 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-194820

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-194820 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-188612

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-188612 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-182404

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-182404 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-176197

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-176197 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-169989

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-169989 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-163781

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-163781 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-157573

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-157573 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-151365

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-151365 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-145157

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-145157 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-138949

P

5.30629e-07

HmolarSmolar

INCONSISTENT

2phase

7.32374e-05

287.842

Hmolar

-240271

Smolar

-539.442

HmolarSmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000100117

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Hmolar

-245094

Smolar

-556.427

HmolarSmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-256900

Smolar

-600.09

HmolarSmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000512279

298.992

Hmolar

-233371

Smolar

-515.922

HmolarSmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000100117

280.046

Hmolar

-245094

Smolar

-556.427

HmolarSmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-138949

Smolar

-148.167

HmolarSmolar

INCONSISTENT

1phase

0.000226469

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000226469

280.046

Hmolar

-245094

Smolar

-556.427

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-600.09

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-600.09 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-576.304

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-576.304 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-552.519

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-552.519 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-528.734

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-528.734 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-504.948

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-504.948 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-481.163

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-481.163 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-457.377

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-457.377 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-433.592

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-433.592 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-409.807

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-409.807 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-386.021

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-386.021 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-362.236

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-362.236 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-338.45

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-338.45 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-314.665

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-314.665 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-290.88

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-290.88 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-267.094

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-267.094 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-243.309

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-243.309 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-219.524

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-219.524 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-195.738

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-195.738 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-171.953

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-171.953 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

INCONSISTENT

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-148.167

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-256900

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-256900 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-250807

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-250807 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-244713

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-244713 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-238619

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-238619 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-232525

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-232525 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-226431

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-226431 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-220338

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-220338 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-214244

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-214244 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-208150

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-208150 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-202056

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-202056 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-195963

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-195963 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-189869

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-189869 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-183775

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-183775 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-177681

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-177681 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-171588

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-171588 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-165494

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-165494 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-159400

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-159400 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-153306

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-153306 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-147212

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-147212 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

INCONSISTENT

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-141119

SmolarT

EXCEPTION

1phase

7.47336e-07

905.269

Smolar

613.312

T

905.269

input 613.312 is not in range 343.247,613.253

SmolarT

EXCEPTION

1phase

7.47336e-07

924.215

Smolar

632.025

T

924.215

input 632.025 is not in range 362.058,631.793

SmolarT

EXCEPTION

1phase

7.47336e-07

943.162

Smolar

650.549

T

943.162

input 650.549 is not in range 380.658,650.149

SmolarT

EXCEPTION

1phase

7.47336e-07

962.108

Smolar

668.888

T

962.108

input 668.888 is not in range 399.053,668.322

SmolarT

EXCEPTION

1phase

7.47336e-07

981.054

Smolar

687.041

T

981.054

input 687.041 is not in range 417.249,686.313

SmolarT

EXCEPTION

1phase

7.47336e-07

1000

Smolar

705.012

T

1000

input 705.012 is not in range 435.249,704.125

SmolarT

INCONSISTENT

1phase

3.82396e-06

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

1.6905e-06

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

8.64993e-06

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

1.95664e-05

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

7.47336e-07

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

4.42599e-05

261.1

Smolar

-599.852

T

261.1

SmolarT

INCONSISTENT

1phase

4.42599e-05

280.046

Smolar

-556.427

T

280.046

SmolarT

INCONSISTENT

1phase

0.000100117

280.046

Smolar

-556.427

T

280.046

SmolarT

INCONSISTENT

1phase

0.155238

336.885

Smolar

-441.591

T

336.885

SmolarT

INCONSISTENT

1phase

0.155238

317.938

Smolar

-477.782

T

317.938

SmolarT

INCONSISTENT

1phase

0.0686277

317.938

Smolar

-477.782

T

317.938

SmolarT

INCONSISTENT

1phase

0.030339

317.938

Smolar

-477.782

T

317.938

SmolarT

INCONSISTENT

1phase

0.000226469

280.046

Smolar

-556.427

T

280.046

SmolarT

INCONSISTENT

1phase

0.351154

298.992

Smolar

-515.922

T

298.992

SmolarT

INCONSISTENT

1phase

0.0686277

298.992

Smolar

-515.922

T

298.992

SmolarT

INCONSISTENT

1phase

0.155238

298.992

Smolar

-515.922

T

298.992

SmolarT

INCONSISTENT

1phase

0.030339

298.992

Smolar

-515.922

T

298.992

SmolarT

INCONSISTENT

1phase

0.0134123

298.992

Smolar

-515.922

T

298.992

SmolarT

INCONSISTENT

1phase

0.0134123

317.938

Smolar

-477.782

T

317.938

SmolarT

INCONSISTENT

1phase

0.000100117

261.1

Smolar

-599.852

T

261.1

Superancillary Plots#

The following figure shows the accuracy of the superancillary functions relative to extended precision calculations carried out in C++ with the teqp library. The results of the iterative calculations with REFPROP and CoolProp are also shown.

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate2.png