MethylLinolenate#

References#

Equation of State#

Marcia L. Huber, Eric W. Lemmon, Andrei Kazakov, Lisa S. Ott, and Thomas J. Bruno. Model for the Thermodynamic Properties of a Biodiesel Fuel. Energy & Fuels, 23:3790–3797, 2009. doi:10.1021/ef900159g.

Aliases#

METHYLLINOLENATE, MLINOLEN

Molecular Structure#

MethylLinolenate — 3D conformer (interactive: click and drag to rotate)

Fluid Information#

Parameter, Value

General

Molar mass [kg/mol]

0.29245618

CAS number

301-00-8

ASHRAE class

UNKNOWN

Formula

C19H32O2

Acentric factor

1.142605258673496

InChI

InChI=1S/C19H32O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h4-5,7-8,10-11H,3,6,9,12-18H2,1-2H3/b5-4-,8-7-,11-10-

InChIKey

DVWSXZIHSUZZKJ-YSTUJMKBSA-N

SMILES

CC/C=CC/C=CC/C=CCCCCCCCC(=O)OC

ChemSpider ID

4477947

Limits

Maximum temperature [K]

1000.0

Maximum pressure [Pa]

50000000.0

Triple point

Triple point temperature [K]

260.0

Triple point pressure [Pa]

\(7.39936963447781\times 10^{-07}\)

Critical point

Critical point temperature [K]

772.0000022320153

Critical point density [kg/m3]

247.7981283034243

Critical point density [mol/m3]

847.300023899048

Critical point pressure [Pa]

1368997.2565422528

REFPROP Validation Data#

Note

This figure compares the results generated from CoolProp and those generated from REFPROP. They are all results obtained in the form \(Y(T,\rho)\), where \(Y\) is the parameter of interest and which for all EOS is a direct evaluation of the EOS

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate.png

Consistency Plots#

The following figure shows all the flash routines that are available for this fluid. A red + is a failure of the flash routine, a black dot is a success. Hopefully you will only see black dots. The red curve is the maximum temperature curve, and the blue curve is the melting line if one is available for the fluid.

In this figure, we start off with a state point given by T,P and then we calculate each of the other possible output pairs in turn, and then try to re-calculate T,P from the new input pair. If we don’t arrive back at the original T,P values, there is a problem in the flash routine in CoolProp. For more information on how these figures were generated, see CoolProp.Plots.ConsistencyPlots

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate1.png

Flash consistency (HEOS): 363 inconsistent, 68 exceptions, 0 bad-phase across 11 input pair(s).

Download full failure list (CSV)

Failing state points (sample, up to 20 per pair/class)

Pair

Class

Region

P [Pa]

T [K]

In1

Val1

In2

Val2

Error

DmolarHmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarHmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Hmolar

-233371

DmolarHmolar

INCONSISTENT

1phase

0.00115879

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

0.000512279

280.046

Dmolar

3108.44

Hmolar

-245094

DmolarHmolar

INCONSISTENT

1phase

0.000512279

261.1

Dmolar

3159.07

Hmolar

-256838

DmolarP

EXCEPTION

1phase

7.47336e-07

261.1

Dmolar

3159.07

P

7.27133e-07

Starting value of T0 is not valid in DP_flash

DmolarP

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

P

9.98586e-05

DmolarP

INCONSISTENT

1phase

0.030339

280.046

Dmolar

3108.44

P

0.0303393

DmolarP

INCONSISTENT

1phase

0.0686277

261.1

Dmolar

3159.07

P

0.0686278

DmolarP

INCONSISTENT

1phase

0.0686277

280.046

Dmolar

3108.44

P

0.0686275

DmolarP

INCONSISTENT

1phase

0.000512279

261.1

Dmolar

3159.07

P

0.000512391

DmolarP

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

P

0.000226038

DmolarP

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

P

4.4202e-05

DmolarP

INCONSISTENT

1phase

0.00262122

298.992

Dmolar

3059.71

P

0.00262129

DmolarP

INCONSISTENT

1phase

0.0059293

317.938

Dmolar

3012.49

P

0.00592924

DmolarP

INCONSISTENT

1phase

0.0134123

280.046

Dmolar

3108.44

P

0.0134125

DmolarP

INCONSISTENT

1phase

0.0134123

261.1

Dmolar

3159.07

P

0.0134124

DmolarP

INCONSISTENT

1phase

0.0059293

280.046

Dmolar

3108.44

P

0.00592914

DmolarP

INCONSISTENT

1phase

0.0059293

261.1

Dmolar

3159.07

P

0.00592914

DmolarP

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

P

1.9376e-05

DmolarP

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

P

2.14028e-06

DmolarP

INCONSISTENT

1phase

0.0686277

317.938

Dmolar

3012.49

P

0.0686275

DmolarP

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

7.6459e-10

P

5.30629e-07

DmolarP

INCONSISTENT

1phase

0.0686277

336.885

Dmolar

2966.42

P

0.0686273

DmolarP

INCONSISTENT

1phase

0.155238

280.046

Dmolar

3108.44

P

0.155239

DmolarP

INCONSISTENT

1phase

0.00262122

280.046

Dmolar

3108.44

P

0.0026217

DmolarSmolar

INCONSISTENT

1phase

0.000226469

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Smolar

-556.427

DmolarSmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Smolar

-599.852

DmolarSmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Smolar

-515.922

DmolarT

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

3159.34

T

261

DmolarT

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

2phase

5.30629e-07

261

Dmolar

2.41449e-10

T

261

DmolarT

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

T

280.046

DmolarT

INCONSISTENT

2phase

7.32374e-05

287.842

Dmolar

3088.18

T

287.842

DmolarT

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

T

261.1

DmolarT

INCONSISTENT

1phase

0.000512279

280.046

Dmolar

3108.44

T

280.046

DmolarT

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

T

280.046

DmolarUmolar

INCONSISTENT

1phase

0.000226469

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000100117

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000226469

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000100117

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Dmolar

3108.44

Umolar

-245094

DmolarUmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Dmolar

3159.07

Umolar

-256838

DmolarUmolar

INCONSISTENT

1phase

0.000512279

298.992

Dmolar

3059.71

Umolar

-233371

DmolarUmolar

INCONSISTENT

1phase

0.000512279

280.046

Dmolar

3108.44

Umolar

-245094

HmolarP

EXCEPTION

1phase

7.47336e-07

261.1

Hmolar

-256838

P

7.27133e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-256838 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-256900

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-256900 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-250692

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-250692 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-244484

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-244484 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-238276

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-238276 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-232068

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-232068 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-225860

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-225860 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-219652

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-219652 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-213444

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-213444 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-207236

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-207236 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-201028

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-201028 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-194820

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-194820 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-188612

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-188612 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-182404

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-182404 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-176197

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-176197 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-169989

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-169989 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-163781

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-163781 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-157573

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-157573 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-151365

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-151365 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

EXCEPTION

2phase

5.30629e-07

261

Hmolar

-145157

P

5.30629e-07

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Hmolar [-145157 J/mol] is below the minimum value of -139328.195727 J/mol

HmolarP

INCONSISTENT

1phase

3.82396e-06

261.1

Hmolar

-256838

P

4.03997e-06

HmolarP

INCONSISTENT

1phase

1.6905e-06

261.1

Hmolar

-256838

P

2.14028e-06

HmolarP

INCONSISTENT

1phase

1.95664e-05

261.1

Hmolar

-256838

P

1.9376e-05

HmolarP

INCONSISTENT

1phase

8.64993e-06

261.1

Hmolar

-256838

P

8.85808e-06

HmolarP

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-138949

P

5.30629e-07

HmolarP

INCONSISTENT

1phase

0.000100117

280.046

Hmolar

-245094

P

9.95438e-05

HmolarP

INCONSISTENT

1phase

4.42599e-05

261.1

Hmolar

-256838

P

4.42066e-05

HmolarSmolar

INCONSISTENT

2phase

7.32374e-05

287.842

Hmolar

-240271

Smolar

-539.442

HmolarSmolar

INCONSISTENT

1phase

1.95664e-05

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000100117

280.046

Hmolar

-245094

Smolar

-556.427

HmolarSmolar

INCONSISTENT

1phase

4.42599e-05

280.046

Hmolar

-245094

Smolar

-556.427

HmolarSmolar

INCONSISTENT

1phase

1.6905e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-256900

Smolar

-600.09

HmolarSmolar

INCONSISTENT

1phase

7.47336e-07

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000512279

298.992

Hmolar

-233371

Smolar

-515.922

HmolarSmolar

INCONSISTENT

1phase

8.64993e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

3.82396e-06

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

4.42599e-05

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

2phase

5.30629e-07

261

Hmolar

-138949

Smolar

-148.167

HmolarSmolar

INCONSISTENT

1phase

0.000100117

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000226469

280.046

Hmolar

-245094

Smolar

-556.427

HmolarSmolar

INCONSISTENT

1phase

0.000226469

261.1

Hmolar

-256838

Smolar

-599.852

HmolarSmolar

INCONSISTENT

1phase

0.000512279

280.046

Hmolar

-245094

Smolar

-556.427

PSmolar

EXCEPTION

1phase

7.47336e-07

261.1

P

7.27133e-07

Smolar

-599.852

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-599.852 J/mol/K] is below the minimum value of -152.349098204 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-600.09

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-600.09 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-576.304

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-576.304 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-552.519

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-552.519 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-528.734

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-528.734 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-504.948

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-504.948 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-481.163

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-481.163 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-457.377

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-457.377 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-433.592

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-433.592 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-409.807

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-409.807 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-386.021

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-386.021 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-362.236

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-362.236 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-338.45

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-338.45 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-314.665

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-314.665 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-290.88

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-290.88 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-267.094

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-267.094 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-243.309

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-243.309 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-219.524

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-219.524 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-195.738

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-195.738 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-171.953

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Smolar [-171.953 J/mol/K] is below the minimum value of -149.729653265 J/mol/K

PSmolar

INCONSISTENT

1phase

1.6905e-06

261.1

P

2.14028e-06

Smolar

-599.852

PSmolar

INCONSISTENT

1phase

8.64993e-06

261.1

P

8.85808e-06

Smolar

-599.852

PSmolar

INCONSISTENT

1phase

1.95664e-05

261.1

P

1.9376e-05

Smolar

-599.852

PSmolar

INCONSISTENT

1phase

3.82396e-06

261.1

P

4.03997e-06

Smolar

-599.852

PSmolar

INCONSISTENT

2phase

5.30629e-07

261

P

5.30629e-07

Smolar

-148.167

PSmolar

INCONSISTENT

1phase

0.000100117

261.1

P

9.98586e-05

Smolar

-599.852

PSmolar

INCONSISTENT

1phase

4.42599e-05

280.046

P

4.4202e-05

Smolar

-556.427

PSmolar

INCONSISTENT

1phase

0.000100117

280.046

P

9.95438e-05

Smolar

-556.427

PSmolar

INCONSISTENT

1phase

0.000226469

280.046

P

0.000226038

Smolar

-556.427

PT

INCONSISTENT

1phase

7.47336e-07

261.1

P

7.27133e-07

T

261.1

PT

INCONSISTENT

1phase

1.95664e-05

261.1

P

1.9376e-05

T

261.1

PT

INCONSISTENT

1phase

1.6905e-06

261.1

P

2.14028e-06

T

261.1

PT

INCONSISTENT

1phase

3.82396e-06

261.1

P

4.03997e-06

T

261.1

PT

INCONSISTENT

1phase

8.64993e-06

261.1

P

8.85808e-06

T

261.1

PT

INCONSISTENT

1phase

0.000226469

280.046

P

0.000226038

T

280.046

PUmolar

EXCEPTION

1phase

7.47336e-07

261.1

P

7.27133e-07

Umolar

-256838

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-256838 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-256900

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-256900 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-250807

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-250807 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-244713

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-244713 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-238619

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-238619 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-232525

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-232525 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-226431

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-226431 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-220338

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-220338 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-214244

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-214244 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-208150

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-208150 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-202056

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-202056 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-195963

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-195963 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-189869

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-189869 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-183775

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-183775 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-177681

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-177681 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-171588

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-171588 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-165494

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-165494 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-159400

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-159400 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-153306

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-153306 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

EXCEPTION

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-147212

unable to solve 1phase PY flash with Tmin=260, Tmax=1500 due to error: HSU_P_flash_singlephase_Brent could not find a solution because Umolar [-147212 J/mol] is below the minimum value of -141489.958447 J/mol

PUmolar

INCONSISTENT

1phase

3.82396e-06

261.1

P

4.03997e-06

Umolar

-256838

PUmolar

INCONSISTENT

1phase

1.95664e-05

261.1

P

1.9376e-05

Umolar

-256838

PUmolar

INCONSISTENT

1phase

1.6905e-06

261.1

P

2.14028e-06

Umolar

-256838

PUmolar

INCONSISTENT

2phase

5.30629e-07

261

P

5.30629e-07

Umolar

-141119

PUmolar

INCONSISTENT

1phase

8.64993e-06

261.1

P

8.85808e-06

Umolar

-256838

PUmolar

INCONSISTENT

1phase

0.000100117

261.1

P

9.98586e-05

Umolar

-256838

SmolarT

EXCEPTION

1phase

7.47336e-07

905.269

Smolar

613.312

T

905.269

argument not found

SmolarT

INCONSISTENT

1phase

7.47336e-07

886.323

Smolar

594.41

T

886.323

SmolarT

INCONSISTENT

1phase

7.47336e-07

867.377

Smolar

575.316

T

867.377

SmolarT

INCONSISTENT

1phase

7.47336e-07

848.431

Smolar

556.03

T

848.431

SmolarT

INCONSISTENT

1phase

7.47336e-07

829.485

Smolar

536.55

T

829.485

SmolarT

INCONSISTENT

1phase

1.6905e-06

981.054

Smolar

680.254

T

981.054

SmolarT

INCONSISTENT

1phase

7.47336e-07

810.538

Smolar

516.874

T

810.538

SmolarT

INCONSISTENT

1phase

7.47336e-07

791.592

Smolar

497.002

T

791.592

SmolarT

INCONSISTENT

1phase

7.47336e-07

772.646

Smolar

476.933

T

772.646

SmolarT

INCONSISTENT

1phase

1.6905e-06

1000

Smolar

698.225

T

1000

SmolarT

INCONSISTENT

1phase

1.6905e-06

791.592

Smolar

490.215

T

791.592

SmolarT

INCONSISTENT

1phase

1.6905e-06

810.538

Smolar

510.087

T

810.538

SmolarT

INCONSISTENT

1phase

1.6905e-06

829.485

Smolar

529.763

T

829.485

SmolarT

INCONSISTENT

1phase

1.6905e-06

848.431

Smolar

549.243

T

848.431

SmolarT

INCONSISTENT

1phase

1.6905e-06

962.108

Smolar

662.101

T

962.108

SmolarT

INCONSISTENT

1phase

1.6905e-06

943.162

Smolar

643.763

T

943.162

SmolarT

INCONSISTENT

1phase

1.6905e-06

924.215

Smolar

625.238

T

924.215

SmolarT

INCONSISTENT

1phase

1.6905e-06

867.377

Smolar

568.529

T

867.377

SmolarT

INCONSISTENT

1phase

1.6905e-06

905.269

Smolar

606.525

T

905.269

SmolarT

INCONSISTENT

1phase

1.6905e-06

886.323

Smolar

587.623

T

886.323

SmolarT

INCONSISTENT

1phase

1.6905e-06

772.646

Smolar

470.146

T

772.646

Superancillary Plots#

The following figure shows the accuracy of the superancillary functions relative to extended precision calculations carried out in C++ with the teqp library. The results of the iterative calculations with REFPROP and CoolProp are also shown.

Note

You can download the script that generated the following figure here: (link to script), right-click the link and then save as… or the equivalent in your browser. You can also download this figure as a PDF.

../../_images/MethylLinolenate2.png